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Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017706853> ?p ?o ?g. }

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• W2017706853 abstract "An explanation of the gel-effect is proposed based on a representation of the change of the type of diffusion in macromolecules in moderately concentrated solution with increasing conversion by taking into account the non-equivalence of contacts of macromolecules of different length. Attention was mainly devoted to the threshold of gel-effect since it can be analyzed separately from other stages. The dependence of this threshold on the macromolecular mass distribution was considered for polymer being formed up to the onset of gel-effect. The conditions estimated from the suggested model for onset of gel-effect correspond with the experimental data. On the basis of this model some conclusions are discussed concerning auto-acceleration in systems containing polymer with bimodal distribution, which can be used for experimental verification and correcting the model." @default.
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• W2017706853 date "1981-01-01" @default.
• W2017706853 modified "2023-10-15" @default.
• W2017706853 title "On the gel-effect mechanism in radical polymerization" @default.
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• W2017706853 doi "https://doi.org/10.1016/0032-3950(81)90065-4" @default.
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