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- W2017720912 abstract "A combined initiator comprising SmI2 and SmI3 has proven to serve as an excellent and convenient bisinitiator for the living polymerization of methyl (MMA) and tert-butyl methacrylates (TBMA). The polymerization of MMA or TBMA with SmI2 in the presence of catalytic amounts of SmI3 led to the quantitative formation of polymers with low polydispersity (M̄w/M̄n = 1.08–1.11). A linear relationship between the feed ratio of the monomers to SmI2 and the M̄n of the polymers was recognized, which implies the absence of chain transfer reactions. The absence of termination was confirmed by the post-polymerization technique in which – after the complete consumption of the initially charged monomer – the second feed of MMA resulted in an increase in M̄n of the polymer maintaining its narrow molecular weight distribution. The initiation efficiency of the living polymerization of MMA was as high as 98%. Functionalization of the end group of living poly(MMA) was also accomplished with various electrophiles to give telechelic polymers." @default.
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- W2017720912 date "2001-06-01" @default.
- W2017720912 modified "2023-09-27" @default.
- W2017720912 title "SmI2/SmI3 as a Convenient Bisinitiator for the Living Polymerization of Methacrylates" @default.
- W2017720912 doi "https://doi.org/10.1002/1521-3935(20010601)202:9<1614::aid-macp1614>3.0.co;2-w" @default.
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