FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017744987> ?p ?o ?g. }

• W2017744987 endingPage "9574" @default.
• W2017744987 startingPage "9566" @default.
• W2017744987 abstract "The chiral organization of an enantiopure functional molecule on an achiral surface has been studied with the aim of understanding the influence of stereogenic centers on the self-assembly in two dimensions. A chiral tetra meso-amidophenyl-substituted porphyrin containing long hydrophobic tails at the periphery of the conjugated π-electron system was prepared for this purpose. Scanning tunneling microscopy (STM) images of the compound at the graphite−heptanol interface reveal a chiral arrangement of the molecules, with the porphyrin rows tilted by 13° with respect to the normal to the graphite axes. In terms of molecular modeling, a combination of molecular dynamics simulations on systems constrained by periodic boundary conditions and on unconstrained large molecular aggregates has been applied to reach a quantitative interpretation on both the density of the layer and its orientation with respect to the graphite surface. The results show clearly that (i) the methyl groups of the stereogenic point toward the graphite surface and (ii) the porphyrin molecules self-assemble into an interdigitated structure where the alkyl chains align along one of the graphite axes and the porphyrin cores are slightly shifted with respect to one another. The direction of this shift, which defines the chirality of the monolayer, is set by the chirality of the stereogenic centers. Such an arrangement results in the formation of a dense chiral monolayer that is further stabilized by hydrogen bonding with protic solvents." @default.
• W2017744987 created "2016-06-24" @default.
• W2017744987 creator A5009277810 @default.
• W2017744987 creator A5014428406 @default.
• W2017744987 creator A5021312773 @default.
• W2017744987 creator A5028154374 @default.
• W2017744987 creator A5049379555 @default.
• W2017744987 creator A5068870927 @default.
• W2017744987 creator A5085874883 @default.
• W2017744987 date "2008-07-24" @default.
• W2017744987 modified "2023-10-09" @default.
• W2017744987 title "Chiral Expression at the Solid−Liquid Interface: A Joint Experimental and Theoretical Study of the Self-Assembly of Chiral Porphyrins on Graphite" @default.
• W2017744987 cites W1942972169 @default.
• W2017744987 cites W1965588050 @default.
• W2017744987 cites W1965972862 @default.
• W2017744987 cites W1970146913 @default.
• W2017744987 cites W1974259538 @default.
• W2017744987 cites W1978487480 @default.
• W2017744987 cites W1981068422 @default.
• W2017744987 cites W1985465446 @default.
• W2017744987 cites W2003833913 @default.
• W2017744987 cites W2004394375 @default.
• W2017744987 cites W2007151621 @default.
• W2017744987 cites W2007416174 @default.
• W2017744987 cites W2007907764 @default.
• W2017744987 cites W2008088081 @default.
• W2017744987 cites W2010933452 @default.
• W2017744987 cites W2019089592 @default.
• W2017744987 cites W2019378323 @default.
• W2017744987 cites W2021901048 @default.
• W2017744987 cites W2023397720 @default.
• W2017744987 cites W2028432053 @default.
• W2017744987 cites W2031783283 @default.
• W2017744987 cites W2033870919 @default.
• W2017744987 cites W2044226967 @default.
• W2017744987 cites W2050221527 @default.
• W2017744987 cites W2051707493 @default.
• W2017744987 cites W2052367576 @default.
• W2017744987 cites W2053424489 @default.
• W2017744987 cites W2060208846 @default.
• W2017744987 cites W2066546105 @default.
• W2017744987 cites W2077162324 @default.
• W2017744987 cites W2080627352 @default.
• W2017744987 cites W2081512968 @default.
• W2017744987 cites W2085834657 @default.
• W2017744987 cites W2122816957 @default.
• W2017744987 cites W2137950460 @default.
• W2017744987 cites W2150059320 @default.
• W2017744987 cites W2152932169 @default.
• W2017744987 cites W2164479654 @default.
• W2017744987 cites W2320871107 @default.
• W2017744987 cites W2333065922 @default.
• W2017744987 cites W2489933306 @default.
• W2017744987 cites W2949473732 @default.
• W2017744987 cites W4211194843 @default.
• W2017744987 cites W4211235335 @default.
• W2017744987 cites W4237401957 @default.
• W2017744987 cites W4254138173 @default.
• W2017744987 cites W1982826935 @default.
• W2017744987 cites W2055971298 @default.
• W2017744987 cites W4243857711 @default.
• W2017744987 doi "https://doi.org/10.1021/la8017419" @default.
• W2017744987 hasPubMedId "https://pubmed.ncbi.nlm.nih.gov/18652420" @default.
• W2017744987 hasPublicationYear "2008" @default.
• W2017744987 type Work @default.
• W2017744987 sameAs 2017744987 @default.
• W2017744987 citedByCount "41" @default.
• W2017744987 countsByYear W20177449872012 @default.
• W2017744987 countsByYear W20177449872013 @default.
• W2017744987 countsByYear W20177449872014 @default.
• W2017744987 countsByYear W20177449872015 @default.
• W2017744987 countsByYear W20177449872016 @default.
• W2017744987 countsByYear W20177449872017 @default.
• W2017744987 countsByYear W20177449872018 @default.
• W2017744987 crossrefType "journal-article" @default.
• W2017744987 hasAuthorship W2017744987A5009277810 @default.
• W2017744987 hasAuthorship W2017744987A5014428406 @default.
• W2017744987 hasAuthorship W2017744987A5021312773 @default.
• W2017744987 hasAuthorship W2017744987A5028154374 @default.
• W2017744987 hasAuthorship W2017744987A5049379555 @default.
• W2017744987 hasAuthorship W2017744987A5068870927 @default.
• W2017744987 hasAuthorship W2017744987A5085874883 @default.
• W2017744987 hasConcept C121332964 @default.
• W2017744987 hasConcept C124668440 @default.
• W2017744987 hasConcept C134195300 @default.
• W2017744987 hasConcept C146686406 @default.
• W2017744987 hasConcept C159467904 @default.
• W2017744987 hasConcept C161790260 @default.
• W2017744987 hasConcept C171250308 @default.
• W2017744987 hasConcept C178790620 @default.
• W2017744987 hasConcept C185592680 @default.
• W2017744987 hasConcept C192562407 @default.
• W2017744987 hasConcept C20621625 @default.
• W2017744987 hasConcept C2777527944 @default.
• W2017744987 hasConcept C2779480358 @default.
• W2017744987 hasConcept C2779698641 @default.
• W2017744987 hasConcept C2780263894 @default.
• W2017744987 hasConcept C32909587 @default.

• next