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- W2017754005 abstract "The chemical bonding topology in the MgB2 superconductor is similar to that in the high Tc cuprates. Thus the conducting skeleton of MgB2 consists of the hexagonal boron layers, which are isoelectronic with graphite if the Mg is oxidized completely to Mg2+. However, comparison of the MgMg distances in MgB2 with those in several ternary hydrides (Mg2RuH4, Mg3RuH3, and Mg4IrH5), assumed to contain subvalent magnesium as Mg22+, suggests similar subvalent magnesium in MgB2. This incomplete oxidation of Mg to Mg2+ generates the holes in the valence band of the hexagonal boron layers leading to the experimentally observed hole superconductivity in MgB2." @default.
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- W2017754005 date "2002-10-01" @default.
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- W2017754005 title "Chemical bonding topology of superconductors. 5. The similarities between magnesium diboride and cuprate superconductors and the role of subvalent magnesium" @default.
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- W2017754005 doi "https://doi.org/10.1016/s0277-5387(02)01183-x" @default.
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