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- W2017754322 abstract "Abstract Some new mixed triorganoantimony(III) compounds bearing pentafluorophenyl and hydrocarbon based organic groups of the type R 2 R′Sb (where R = C 6 F 5 , R′ = CH 3 , C 6 H 4 CH 3 - p , C 6 H 5 ; R = C 6 H 5 , R′ = C 6 F 5 ) were synthesized using either appropriate organomagnesium halide and pentafluorophenylantimony(III) chloride or pentafluorophenylmagnesium bromide and organoantimony(III) chloride. These derivatives undergo oxidative-addition reaction with halogens (Br, Cl) yielding corresponding triorganoantimony(V) dihalides. The van’t Hoff factor ‘ i ’ and molar conductance data of these compounds revealed them to be monomeric and non-conducting in nature. The compounds were characterized by the elemental analysis, IR, NMR ( 1 H, 13 C and 19 F) and FAB mass analysis." @default.
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- W2017754322 date "2006-04-01" @default.
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- W2017754322 title "Synthesis and characterization of some new mixed pentafluorophenyl organoantimony(III and V) derivatives" @default.
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- W2017754322 doi "https://doi.org/10.1016/j.poly.2005.09.027" @default.
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