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• W2017758239 abstract "The kinetics of the oxidation of L-cystine by the di-oxo-bridged Co(III) complex have been studied at various temperatures, 298 K to 323 K, and pH, 3.30 to 4.45, using UV−vis spectroscopy in NaClO4 medium. The product of the reaction has been characterized by UV-vis spectra, IR, and 1H NMR spectroscopy. The activation parameters such as enthalpy, entropy, free energy, and activation energy have been evaluated. A new SNi mechanism has been derived for this reaction. The oxidation product was found to be cystine disulfoxide, R-SO-SO-R at T ≤ 318 K and disulfone, R- (SO2)2-R at T = 323 K. Supplemental materials are available for this article. Go to the publisher's online edition of Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry to view the supplemental file." @default.
• W2017758239 created "2016-06-24" @default.
• W2017758239 creator A5080035188 @default.
• W2017758239 date "2013-02-26" @default.
• W2017758239 modified "2023-09-25" @default.
• W2017758239 title "Synthesis and Reactivity of L-Cystine with Di-Oxo-Bridged Cobalt(III) Complex" @default.
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• W2017758239 doi "https://doi.org/10.1080/15533174.2012.740745" @default.
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