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• W2017759733 abstract "The new organosulfur ligands siS3-H2 [siS32− = bis(2-mercapto-3-trimethylsilylphenyl) sulfide(2−)] and caS3-H2 [caS32− = bis(2-mercapto-3-carboxyphenyl) sulfide(2−)] were synthesized from HS3-H2 [HS32− = bis(2-mercaptophenyl) sulfide(2−)], n-butyllithium, and Me3SiCl or CO2/H+. Reaction of siS3-H2 with Ni(ac)2·4H2O gave the air-stable and well-soluble trinuclear complex [Ni(siS3)]3 (1) whose structure was determined by X-ray crystallography. Reactions of complex 1 with nucleophiles L [L = PR3 (R = nPr, Ph, Cy), N2H4, StBu−, and Cl−] yielded the corresponding neutral or anionic complexes, which were isolated as [Ni(PR3)(siS3)] [R = nPr (2), Ph (3), Cy (4)], Bu4N[Ni(Cl)(siS3)] (5), Bu4N[Ni(StBu)(siS3)] (6), and [Ni(N2H4)(siS3)] (8). The azido complex Et4N[Ni(N3)(siS3)] (7) was prepared from Me3SiN3 and the precursor chloro complex Et4N[Ni(Cl)(siS3)]. Reaction of 1 with NH3 yielded labile [Ni(NH3)(siS3)] (9), which was characterized in solution by 1H and 13C NMR spectroscopy. Analogously, 1 reacts with nicotinamide (NA) or diethylnicotinamide (NAEt2) to give, from equilibrium reactions, the corresponding mononuclear [Ni(L)(siS3)] complexes with L = NA, NAEt2. X-ray structure determinations showed that 1, 3, 4, 5, and 7 all exhibit tetrahedrally distorted planar [Ni(L)(siS3)] fragments. Complex 7 is the first structurally characterized azidonickel complex with a coligand having exclusively sulfur donors. (© Wiley-VCH Verlag GmbH, 69451 Weinheim, Germany, 2002)" @default.
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• W2017759733 date "2002-08-01" @default.
• W2017759733 modified "2023-10-17" @default.
• W2017759733 title "Highly Soluble Sulfur-Rich [Ni(L)(siS3)] Complexes Containing the New Ligand Bis(2-mercapto-3-trimethylsilylphenyl) Sulfide(2−) (siS32−)" @default.
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• W2017759733 doi "https://doi.org/10.1002/1099-0682(200208)2002:8<2138::aid-ejic2138>3.0.co;2-h" @default.
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