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- W2017767029 abstract "The potential of zero charge (pzc) of Pd(1 1 1) has been determined in dilute NaF solutions by measuring the Gouy–Chapman minimum of the double-layer capacity. For a massive Pd(1 1 1) single crystal electrode a pzc of −0.12 V vs. SCE has been found. The corresponding values for thin Pd(1 1 1) overlayers on Au(1 1 1) have also been determined. While the pzc of the first, pseudomorphic Pd layer on Au(1 1 1) is −0.09 V vs. SCE, the pzc of a five monolayers thick Pd film on Au(1 1 1) is practically identical to the pzc of the massive Pd(1 1 1) electrode. By comparing pzc's and work functions for Au(1 1 1) and Pd(1 1 1), the dipole contribution to the potential drop across the Pd(1 1 1)/water interface is estimated." @default.
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- W2017767029 date "2002-07-01" @default.
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- W2017767029 title "The potentials of zero charge of Pd(111) and thin Pd overlayers on Au(111)" @default.
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- W2017767029 doi "https://doi.org/10.1016/s1388-2481(02)00362-4" @default.
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