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• W2017784085 startingPage "5693" @default.
• W2017784085 abstract "An electron-excited x-ray-emission spectrum of oxygen Kensuremath{alpha} is presented for boron suboxide ${mathrm{B}}_{6}$O (isostructural with ${mathrm{B}}_{13}$${mathrm{C}}_{2}$). The spectrum is compared with those calculated by the discrete-variation Xensuremath{alpha} (DV-Xensuremath{alpha}) method with various O-O distances as an adjustable parameter in the fixed icosahedral ${mathrm{B}}_{12}$ framework. The observed spectrum is reproduced well when the O-O distance is in the range 2.5--3.5 AA{}. This O-O bond length is more than twice as long as that of a free ${mathrm{O}}_{2}$ molecule. The oxygen atom is located very close to the center of the boron triangle (closed three-center bond). These results support the structure determined by x-ray structural analysis." @default.
• W2017784085 created "2016-06-24" @default.
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• W2017784085 date "1990-09-15" @default.
• W2017784085 modified "2023-09-23" @default.
• W2017784085 title "Site determination of oxygen in<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msub><mml:mrow><mml:mi mathvariant=normal>B</mml:mi></mml:mrow><mml:mrow><mml:mn>6</mml:mn></mml:mrow></mml:msub></mml:mrow></mml:math>O by oxygen<i>K</i>α x-ray-emission spectroscopy" @default.
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• W2017784085 doi "https://doi.org/10.1103/physrevb.42.5693" @default.
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