FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017785343> ?p ?o ?g. }

• W2017785343 endingPage "412" @default.
• W2017785343 startingPage "399" @default.
• W2017785343 abstract "The relative concentrations of hydrogen atoms were measured during the oscillatory ignition of hydrogen in a well stirred flow reactor. Comparisons were made with the experimental concentration—time profiles of the hydroxyl radical obtained previously under similar experimental conditions. The predicted concentration profiles obtained from numerical analysis of a thermokinetic model were also compared with the experimental results. Experiments were performed in a 600 cm 3 Pyrex glass, jet-stirred reactor with the reactants, 2H 2 + O 2 , at a total pressure of 16 Torr ( ca . 2132.8 Pa) and at a vessel temperature of 753 K. The mean residence time was 1.2 s. Oscillatory ignition was established at a period of 3 s in which high radical concentrations were attained and in which the temperature rise was almost adiabatic. The concentration-time profile of hydrogen atoms was obtained by a resonance enhanced multiphoton ionization (rempi) which was induced by a laser pulse at energies in the vicinity of 364 nm, with ion collection at a stainless steel probe inserted into the reactor. Supplementary studies were made to characterize the signals and to identify effects of the probe within the reaction volume. A measurement of the relative concentrations of hydrogen atoms was obtained from an integration of the area of the rempi spectrum determined over the laser wavelength range 363.8-364.6 nm. The spectrum was measured at successive times in the oscillatory cycle by imposing a variable delay on the laser firing signal. The results show that, during oscillatory ignition, the maximum concentration of hydrogen atoms was reached and a sharp decay was already well advanced before that of the hydroxyl radicals was attained. The numerical analysis was in very good quantitative accord with this experimental result. The phase difference of the cyclic variation in the H atoms relative to that of OH radicals is a key feature of the kinetic mechanisms which control the oscillatory oxidation of hydrogen." @default.
• W2017785343 created "2016-06-24" @default.
• W2017785343 date "1991-08-08" @default.
• W2017785343 modified "2023-09-26" @default.
• W2017785343 title "The application of resonance enhanced multiphoton ionization to the detection of hydrogen atoms during the oscillatory combustion of hydrogen" @default.
• W2017785343 cites W1965084991 @default.
• W2017785343 cites W1971746354 @default.
• W2017785343 cites W1983826219 @default.
• W2017785343 cites W1990800271 @default.
• W2017785343 cites W1992167703 @default.
• W2017785343 cites W1995205737 @default.
• W2017785343 cites W1997448892 @default.
• W2017785343 cites W2002124217 @default.
• W2017785343 cites W2002169029 @default.
• W2017785343 cites W2009932010 @default.
• W2017785343 cites W2010247986 @default.
• W2017785343 cites W2014314849 @default.
• W2017785343 cites W2017061912 @default.
• W2017785343 cites W2023387968 @default.
• W2017785343 cites W2027972240 @default.
• W2017785343 cites W2037054643 @default.
• W2017785343 cites W2043196938 @default.
• W2017785343 cites W2044464293 @default.
• W2017785343 cites W2063995217 @default.
• W2017785343 cites W2071198270 @default.
• W2017785343 cites W2083500947 @default.
• W2017785343 cites W2113235170 @default.
• W2017785343 cites W2139088854 @default.
• W2017785343 cites W2144039520 @default.
• W2017785343 cites W2147495530 @default.
• W2017785343 cites W4241359991 @default.
• W2017785343 doi "https://doi.org/10.1098/rspa.1991.0099" @default.
• W2017785343 hasPublicationYear "1991" @default.
• W2017785343 type Work @default.
• W2017785343 sameAs 2017785343 @default.
• W2017785343 citedByCount "6" @default.
• W2017785343 countsByYear W20177853432018 @default.
• W2017785343 countsByYear W20177853432021 @default.
• W2017785343 crossrefType "journal-article" @default.
• W2017785343 hasConcept C105923489 @default.
• W2017785343 hasConcept C109663097 @default.
• W2017785343 hasConcept C113196181 @default.
• W2017785343 hasConcept C120665830 @default.
• W2017785343 hasConcept C121332964 @default.
• W2017785343 hasConcept C145148216 @default.
• W2017785343 hasConcept C158749347 @default.
• W2017785343 hasConcept C159063594 @default.
• W2017785343 hasConcept C178790620 @default.
• W2017785343 hasConcept C184779094 @default.
• W2017785343 hasConcept C185592680 @default.
• W2017785343 hasConcept C192562407 @default.
• W2017785343 hasConcept C198291218 @default.
• W2017785343 hasConcept C20556612 @default.
• W2017785343 hasConcept C2779545503 @default.
• W2017785343 hasConcept C30646810 @default.
• W2017785343 hasConcept C43617362 @default.
• W2017785343 hasConcept C512968161 @default.
• W2017785343 hasConcept C520434653 @default.
• W2017785343 hasConcept C97355855 @default.
• W2017785343 hasConceptScore W2017785343C105923489 @default.
• W2017785343 hasConceptScore W2017785343C109663097 @default.
• W2017785343 hasConceptScore W2017785343C113196181 @default.
• W2017785343 hasConceptScore W2017785343C120665830 @default.
• W2017785343 hasConceptScore W2017785343C121332964 @default.
• W2017785343 hasConceptScore W2017785343C145148216 @default.
• W2017785343 hasConceptScore W2017785343C158749347 @default.
• W2017785343 hasConceptScore W2017785343C159063594 @default.
• W2017785343 hasConceptScore W2017785343C178790620 @default.
• W2017785343 hasConceptScore W2017785343C184779094 @default.
• W2017785343 hasConceptScore W2017785343C185592680 @default.
• W2017785343 hasConceptScore W2017785343C192562407 @default.
• W2017785343 hasConceptScore W2017785343C198291218 @default.
• W2017785343 hasConceptScore W2017785343C20556612 @default.
• W2017785343 hasConceptScore W2017785343C2779545503 @default.
• W2017785343 hasConceptScore W2017785343C30646810 @default.
• W2017785343 hasConceptScore W2017785343C43617362 @default.
• W2017785343 hasConceptScore W2017785343C512968161 @default.
• W2017785343 hasConceptScore W2017785343C520434653 @default.
• W2017785343 hasConceptScore W2017785343C97355855 @default.
• W2017785343 hasIssue "1891" @default.
• W2017785343 hasLocation W20177853431 @default.
• W2017785343 hasOpenAccess W2017785343 @default.
• W2017785343 hasPrimaryLocation W20177853431 @default.
• W2017785343 hasRelatedWork W1494751507 @default.
• W2017785343 hasRelatedWork W2031087533 @default.
• W2017785343 hasRelatedWork W2031233457 @default.
• W2017785343 hasRelatedWork W2051737324 @default.
• W2017785343 hasRelatedWork W2068532118 @default.
• W2017785343 hasRelatedWork W2094183573 @default.
• W2017785343 hasRelatedWork W2150523788 @default.
• W2017785343 hasRelatedWork W4321451409 @default.
• W2017785343 hasRelatedWork W979418588 @default.
• W2017785343 hasRelatedWork W1993963714 @default.
• W2017785343 hasVolume "434" @default.
• W2017785343 isParatext "false" @default.
• W2017785343 isRetracted "false" @default.
• W2017785343 magId "2017785343" @default.
• W2017785343 workType "article" @default.