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- W2017788116 abstract "Abstract On laser flash photolysis, by direct light absorption as well as under energy transfer sensitization by aromatic ketone triplets, 2,2-dicyano-3-(2-naphthyl)oxirane in fluid solutions forms an ylide characterized by broad and intense absorption spectra (λmax = 610 nm, ϵmax = 2.0 × 104 M−1 cm−1 in benzene) and unusually long lifetimes in aprotic solvents (τY = 130 μs in benzene). The ylide reacts with water, alcohols and dipolarophiles with rate constants that are atypically low (103 – 106 M−1 s−1). The reactivity follows a trend parallel to that of acidity of alcohols and opposite to that of electron-rich character of dipolarophiles." @default.
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- W2017788116 date "1984-12-01" @default.
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- W2017788116 title "Transient spectral and kinetic behaviors of carbonyl ylide photogenerated from 2,2-dicyano-3-(2-naphthyl)-oxirane" @default.
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