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- W2017790377 abstract "A novel organometallic compound, ethyltriphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate (III), abbreviated as TPEPADT, was synthesized. The TPEPADT doped poly(methyl methacrylate) (PMMA) thin film with a mass fraction of 1% (1 wt.%) was prepared by using a spin-coating method. The third-order nonlinear optical properties of TPEPADT in acetonitrile solution and TPEPADT-doped PMMA thin film were investigated by using the laser Z-scan technique at the wavelength 1064 nm with laser duration of 20 ps. The linear refractive index of the polymer thin film was also studied. The Z-scan curves revealed that both TPEPADT in acetonitrile solution and the polymer thin film possessed negative nonlinear refraction, exhibiting a self-defocusing effect and nonlinear absorption was negligible under the experimental conditions used. The nonlinear refractive index was calculated to be −1.9 × 10−18 m2/W for TPEPADT in acetonitrile solution and −8.9 × 10−15 m2/W for the polymer thin film. These results suggest that TPEPADT have potential for the application of all-optical switching devices." @default.
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- W2017790377 date "2012-10-01" @default.
- W2017790377 modified "2023-09-27" @default.
- W2017790377 title "Third order nonlinear optical properties of ethyltriphenylphosphonium bis(2-thioxo-1,3-dithiole-4,5-dithiolato)aurate (III)" @default.
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- W2017790377 doi "https://doi.org/10.1016/j.ijleo.2011.11.062" @default.
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