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• W2017790815 abstract "A concise, enantioselective synthesis of (+)-dumetorine is described, giving the natural product in six steps and a 27% overall yield from a readily available precursor. Among the key steps used, the synthesis entails a high-yielding ring-rearrangement metathesis (RRM), using the commercially available first generation Grubbs catalyst 2 in combination with Ti(Oi–Pr)4 as a co-catalyst. This constitutes the first enantioselective total synthesis of the alkaloid from a known chiral intermediate, and hence a confirmation of its absolute stereochemistry." @default.
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• W2017790815 date "2006-11-01" @default.
• W2017790815 modified "2023-10-03" @default.
• W2017790815 title "Catalytic enantioselective total synthesis of (+)-dumetorine by ring-rearrangement metathesis" @default.
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• W2017790815 doi "https://doi.org/10.1016/j.tetlet.2006.08.114" @default.
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