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- W2017794877 abstract "Thin films of La0.7Sr0.3MnO3 and La0.7Sr0.3FeO3 have been deposited on single crystal yttria-stabilized zirconia (YSZ) substrates using molecular beam epitaxy. Due to the large lattice mismatch, three-dimensional growth is observed with strain relaxation occurring within 1-2 unit cells. The as-grown perovskite/YSZ interfaces are abrupt, despite the imperfections associated with strain relaxation. The films exhibit a single crystallographic orientation along the growth direction, with the perovskite [011] parallel to the YSZ [001]. Synchrotron diffraction and plan view transmission electron microscopy reveal the presence of a columnar grain structure with the in-plane [100] and [] film directions preferentially orientated along the YSZ ⟨100⟩. The stabilization of perovskites on YSZ substrates with abrupt interfaces and a well-defined crystallographic orientation allows for the use of thin film model systems to study cathode/electrolyte interfacial reactions and morphological changes relevant to solid oxide fuel cells." @default.
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- W2017794877 date "2012-01-01" @default.
- W2017794877 modified "2023-09-29" @default.
- W2017794877 title "Structural Investigation of Perovskite Manganite and Ferrite Films on Yttria-Stabilized Zirconia Substrates" @default.
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- W2017794877 doi "https://doi.org/10.1149/2.032208jes" @default.
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