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- W2017795085 abstract "The syntheses of several vinylidene - and ethynyl -ruthenium complexes are described, starting from HC2SiMe3 and RuCl (L)2(η-C5H5)(L= PPh3, PMe3; L2 = dppe ). Their properties and some reactions are reported. The metallacyclic complex [ Ru {C4H2(SiMe3)2}(PMe3)(η-C5H5)][PF6] has also been isolated. The unsubstituted complexes are very reactive; for example, MeOH adds rapidly to the vinylidene to form the C(OMe)Me derivative." @default.
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- W2017795085 date "1991-01-01" @default.
- W2017795085 modified "2023-09-25" @default.
- W2017795085 title "Cyclopentadienyl-ruthenium and -osmium Chemistry. XXXV. Some Ethynyl, Vinylidene and Related Complexes" @default.
- W2017795085 doi "https://doi.org/10.1071/ch9910207" @default.
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