FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017804410> ?p ?o ?g. }

• W2017804410 endingPage "290" @default.
• W2017804410 startingPage "269" @default.
• W2017804410 abstract "Based on the table of the effective ionic radii of R. D. Shannon (Acta Crystallogr. Sect. A32, 751, 1976), the linear relation of the cationic radii on the coordination numberk has been observed:rk=r0+dk−0.0236kz,wherer0 is the radius of free cation, z its valence, andd = 0.1177 - 0.0081 z - 0.0347 r0 - 0.0050 zr0. The analogous relation for O2− anion has been found to ber′k′ = r′0 + a′k′ = 1.328 + 0.0118 k′. By addingrk andr′k′ corresponding to the same bond strength new dependence between bond lengthR and bond strengths has been established for cation-oxygen bonds:s=dzR−R0,whereR0 = r0 + r′0. The necessity to choose a standard state for ionic radii and for bond strength is pointed out and argued. Structures of simple oxides at room temperature and at normal pressure are chosen as standard state at which the sum of the strengths of bonds around the cation is assumed to be exactly equal to itsz.Standard radii of free ions r0 are determined for about 230 ions and are listed. As in Shannon's table some ionic radii were found to be negative. Physical sense can be hardly attributed to this finding. To avoid the negative radii a new scale ofabsolute ionic radiiρ0 is proposed, based on assumption thatρ0(H1+) = 0 instead ofr0(H1+) = −h = −0.499 (the size of the proton is known to be of the order of 10−5A˚, i.e., much less than the accuracy of determination of ionic radii). Consequentlyρ0 for all cations is assumed to beρ0 = r0 + h and for anionsρ′0 = r′0 − h (e.g.,ρ′0(O2−) = 0.829A˚). Bond-length-bond-strength relationship expressed by the equation indicated above is rationalized in terms of the new proposedelectrostatic hover model of crystal structure. In this model ions are of constant size (r0 orρ0), they do not touch each other, but they are maintained at distancesL = R - R0 by the electrostatic forces. This remains in agreement with the suggested (J. Zio´ŀkowski,J. Catal.84, 317, (1983)) linear relation between bond strength and bond energyE = Js which will be proved in the forthcoming paper (J. Zio´ŀkowski and L. Dziembaj,J. Solid State Chem.57, 291 (1985))." @default.
• W2017804410 created "2016-06-24" @default.
• W2017804410 creator A5046314515 @default.
• W2017804410 date "1985-05-01" @default.
• W2017804410 modified "2023-10-11" @default.
• W2017804410 title "New relation between ionic radii, bond length, and bond strength" @default.
• W2017804410 cites W1963854427 @default.
• W2017804410 cites W1972025735 @default.
• W2017804410 cites W1973779645 @default.
• W2017804410 cites W1980015833 @default.
• W2017804410 cites W2004648489 @default.
• W2017804410 cites W2005271162 @default.
• W2017804410 cites W2009462653 @default.
• W2017804410 cites W2014416110 @default.
• W2017804410 cites W2020483037 @default.
• W2017804410 cites W2032554004 @default.
• W2017804410 cites W2035297392 @default.
• W2017804410 cites W2039313117 @default.
• W2017804410 cites W2049331323 @default.
• W2017804410 cites W2054713879 @default.
• W2017804410 cites W2059261065 @default.
• W2017804410 cites W2071883351 @default.
• W2017804410 cites W2089306794 @default.
• W2017804410 cites W2093383683 @default.
• W2017804410 cites W2130100508 @default.
• W2017804410 cites W2158992614 @default.
• W2017804410 cites W2167590372 @default.
• W2017804410 cites W2312201898 @default.
• W2017804410 cites W2316255376 @default.
• W2017804410 doi "https://doi.org/10.1016/0022-4596(85)90152-5" @default.
• W2017804410 hasPublicationYear "1985" @default.
• W2017804410 type Work @default.
• W2017804410 sameAs 2017804410 @default.
• W2017804410 citedByCount "82" @default.
• W2017804410 countsByYear W20178044102012 @default.
• W2017804410 countsByYear W20178044102013 @default.
• W2017804410 countsByYear W20178044102014 @default.
• W2017804410 countsByYear W20178044102015 @default.
• W2017804410 countsByYear W20178044102016 @default.
• W2017804410 countsByYear W20178044102017 @default.
• W2017804410 countsByYear W20178044102019 @default.
• W2017804410 countsByYear W20178044102021 @default.
• W2017804410 countsByYear W20178044102022 @default.
• W2017804410 countsByYear W20178044102023 @default.
• W2017804410 crossrefType "journal-article" @default.
• W2017804410 hasAuthorship W2017804410A5046314515 @default.
• W2017804410 hasConcept C115624301 @default.
• W2017804410 hasConcept C121332964 @default.
• W2017804410 hasConcept C145148216 @default.
• W2017804410 hasConcept C147789679 @default.
• W2017804410 hasConcept C155860418 @default.
• W2017804410 hasConcept C159096172 @default.
• W2017804410 hasConcept C168900304 @default.
• W2017804410 hasConcept C178790620 @default.
• W2017804410 hasConcept C184651966 @default.
• W2017804410 hasConcept C185592680 @default.
• W2017804410 hasConcept C187428577 @default.
• W2017804410 hasConcept C2182769 @default.
• W2017804410 hasConcept C2779227376 @default.
• W2017804410 hasConcept C54998646 @default.
• W2017804410 hasConcept C68928338 @default.
• W2017804410 hasConcept C71100877 @default.
• W2017804410 hasConcept C8010536 @default.
• W2017804410 hasConcept C97355855 @default.
• W2017804410 hasConceptScore W2017804410C115624301 @default.
• W2017804410 hasConceptScore W2017804410C121332964 @default.
• W2017804410 hasConceptScore W2017804410C145148216 @default.
• W2017804410 hasConceptScore W2017804410C147789679 @default.
• W2017804410 hasConceptScore W2017804410C155860418 @default.
• W2017804410 hasConceptScore W2017804410C159096172 @default.
• W2017804410 hasConceptScore W2017804410C168900304 @default.
• W2017804410 hasConceptScore W2017804410C178790620 @default.
• W2017804410 hasConceptScore W2017804410C184651966 @default.
• W2017804410 hasConceptScore W2017804410C185592680 @default.
• W2017804410 hasConceptScore W2017804410C187428577 @default.
• W2017804410 hasConceptScore W2017804410C2182769 @default.
• W2017804410 hasConceptScore W2017804410C2779227376 @default.
• W2017804410 hasConceptScore W2017804410C54998646 @default.
• W2017804410 hasConceptScore W2017804410C68928338 @default.
• W2017804410 hasConceptScore W2017804410C71100877 @default.
• W2017804410 hasConceptScore W2017804410C8010536 @default.
• W2017804410 hasConceptScore W2017804410C97355855 @default.
• W2017804410 hasIssue "3" @default.
• W2017804410 hasLocation W20178044101 @default.
• W2017804410 hasOpenAccess W2017804410 @default.
• W2017804410 hasPrimaryLocation W20178044101 @default.
• W2017804410 hasRelatedWork W1614745653 @default.
• W2017804410 hasRelatedWork W1998140949 @default.
• W2017804410 hasRelatedWork W2048775422 @default.
• W2017804410 hasRelatedWork W2054257808 @default.
• W2017804410 hasRelatedWork W2074947135 @default.
• W2017804410 hasRelatedWork W2122387981 @default.
• W2017804410 hasRelatedWork W2375620005 @default.
• W2017804410 hasRelatedWork W23836609 @default.
• W2017804410 hasRelatedWork W4294770408 @default.
• W2017804410 hasRelatedWork W651190749 @default.
• W2017804410 hasVolume "57" @default.
• W2017804410 isParatext "false" @default.

• next