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- W2017804837 abstract "Abstract A rheological study of 25% poloxamer 407 aqueous solutions was undertaken during sol-gel and dehydration processes. Upon the sol-gel transition, the solution changed from a Newtonian to non-Newtonian fluid through the mechanism of desolvation. During such a desolvation process, the closer approach of polymer chains, which gave rise to an increase in the number of interactions among the chains, was reflected by an increase in solution viscosity with temperature. In this study, three temperature regions, namely, the unimer, transition, and micelle regions originally derived from the light scattering technique, were also demonstrated. The boundary temperatures were 10°C between the unimer and transition regions and 18°C between the transition and micelle regions. Once the gel had been formed above the boundary temperature 18°C, the indices K and n remaining nearly constant, the gel structure was thought to remain unaltered with temperature until an excessively high temperature caused the destruction of the gel structure. At room temperature, the gel underwent a process of dehydration, the evaporation of water from the surface layer occurring first, and eventually dried to a solid. It was found that polyoxyethylene crystals precipitated in the gel during dehydration." @default.
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- W2017804837 title "Rheological behavior of poloxamer 407 aqueous solutions during sol-gel and dehydration processes" @default.
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- W2017804837 doi "https://doi.org/10.1016/0378-5173(94)90445-6" @default.
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