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- W2017807256 abstract "Abstract Complex amphiphilic polymers were synthesized via core‐first polymerization followed by alkylation‐based grafting of poly(ethylene oxide) (PEO). Inimer 1‐(4′‐(bromomethyl)benzyloxy)‐2,3,5,6‐tetrafluoro‐4‐vinylbenzene was synthesized and subjected to atom transfer radical self‐condensing vinyl polymerization to afford hyperbranched fluoropolymer (HBFP) as the hydrophobic core component with a number‐averaged molecular weight of 29 kDa and polydispersity index of 2.1. The alkyl halide chain ends on the HBFP were allowed to undergo reaction with monomethoxy‐terminated poly(ethylene oxide) amine (PEO x ‐NH 2 ) at different grafting numbers and PEO chain lengths to afford PEO‐functionalized HBFPs [(PEO x ) y ‐HBFPs], with x = 15 while y = 16, 22, or 29, x = 44 while y = 16, and x = 112 while y = 16. The amphiphilic, grafted block copolymers were found to aggregate in aqueous solution to give micelles with number‐averaged diameters ( D av ) of 12–28 nm, as measured by transmission electron microscopy (TEM). An increase of the PEO:HBFP ratio, by increase in either the grafting densities ( y values) or the chain lengths ( x values), led to decreased TEM‐measured diameters. These complex, amphiphilic (PEO x ) y ‐HBFPs, with tunable sizes, might find potential applications as nanoscopic biomedical devices, such as drug delivery vehicles and 19 F magnetic resonance imaging agents. © 2010 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 48: 3487–3496, 2010" @default.
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- W2017807256 date "2010-06-25" @default.
- W2017807256 modified "2023-10-18" @default.
- W2017807256 title "Synthesis, characterization, and aqueous self-assembly of amphiphilic poly(ethylene oxide)-functionalized hyperbranched fluoropolymers" @default.
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- W2017807256 doi "https://doi.org/10.1002/pola.24149" @default.
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