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- W2017812411 abstract "The stereoisogram approach is introduced to settle the misleading terminology due to ‘prochirality’ in modern stereochemistry. After the term prochirality is redefined as having a purely geometric meaning, a method based on probe stereoisograms and another method based on equivalence classes (orbits) are introduced to determine prochirality and/or pro-RS-stereogenicity. Enantiotopic and RS-diastereotopic relationships appearing in probe stereoisograms are respectively used to determine prochirality and pro-RS-stereogenicity, where ‘stereoheterotopic’ relationships used in modern stereochemistry are abandoned. Alternatively, an enantiospheric orbit for specifying prochirality and an RS-enantiotropic orbit for specifying pro-RS-stereogenicity are emphasized by using coset representations and Young tableaux. The pro-R/pro-S-system is clarified to be based on pro-RS-stereogenicity and not on prochirality." @default.
- W2017812411 created "2016-06-24" @default.
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- W2017812411 date "2014-09-01" @default.
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- W2017812411 title "Stereoisograms for reorganizing the theoretical foundations of stereochemistry and stereoisomerism. Part 3: rational avoidance of misleading standpoints for pro-R/pro-S-descriptors" @default.
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- W2017812411 doi "https://doi.org/10.1016/j.tetasy.2014.07.010" @default.
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