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- W2017813581 abstract "Infra-red spectra of the nitroammine cobalt (III) complexes, [Co(NO2)n(NH3)6−n](3−n)+ (n = 0, 1, 2, …, 6), have been measured down to 80 cm−1. Vibration frequencies have been calculated for trans- and cis-[Co(NO2)2(NH3)4]+ and [Co(NO2)(NH3)5]2+, using the force constants determined for [Co(NO2)6]3− and [Co(NH3)6]3+. Characteristic frequencies and normal modes of vibrations in the low frequency region have been discussed for this series of complexes, on the basis of the normal coordinate treatment. It has been found that the stereoisomers of the complex reveal quite a different far infra-red spectrum. A detailed vibration analysis for the Na3[Co(NO2)6] on the basis of the S6 twisted form has been made and the structure of [Co(NO2)6]3− ion in this complex salt has been estimated." @default.
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- W2017813581 date "1967-07-01" @default.
- W2017813581 modified "2023-09-27" @default.
- W2017813581 title "Infra-red spectra and structures of nitroammine cobalt (III) complexes" @default.
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