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- W2017834575 abstract "The structural relationship between zircon- and scheelite-type compounds is discussed. Both structures show identical oxygen coordination of A- and B-ions (8 and 4), the scheelite structure however is more densely packed than the zircon structure and has a layer-like arrangement of the cations. This is in agreement with the thermal expansion results which showed that, generally, all scheelite compounds have much higher thermal expansion in the c-direction than corresponding zircon compounds. The magnitude of the thermal expansion is determined primarily by the cation valencies. Compounds containing uni- or divalent A-ions had much higher thermal expansion than compounds with 4-valent cations. The highest thermal expansion coefficients were found for NaIO4(S), CaCrO4(Z) and for the scheelite-type tungstates. ThGeO4(Z) had the lowest thermal expansion of all compounds investigated, followed by TaBO4." @default.
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- W2017834575 date "1972-02-01" @default.
- W2017834575 modified "2023-10-15" @default.
- W2017834575 title "Thermal expansion of ABO4-compounds with zircon- and scheelite structures" @default.
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- W2017834575 doi "https://doi.org/10.1016/0022-5088(72)90045-8" @default.
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