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- W2017854489 abstract "Organic quinone polymers containing sulphonic acid functional groups, combined with palladium ion, gave heterogeneous oxidation catalysts which are effective for the selective oxidation of ethylene to acetaldehyde. Two forms of the resins, soluble or insoluble in water, were made by use of differ- ent networks of cross-linked polymers. Both polymer-anchored palladium catalysts showed stable activities for the ethylene oxidation without any co-catalyst such as CuCl2. The rates and reaction kinetics to form acetaldehyde were determined. The effect of the combination of Pd(II) with polyquinone on the catalytic reaction, and a comparison of the anchored catalysts with a homogeneous catalyst PdCl2-CuCl2 are discussed." @default.
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- W2017854489 title "Catalytic oxidation of ethylene using functional quinone-polymer-anchored palladium catalysts" @default.
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- W2017854489 doi "https://doi.org/10.1016/0304-5102(78)85005-6" @default.
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