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- W2017859499 abstract "Abstract The first synthesis of the 5,5‐difluoro‐(12 R )‐ and ‐(12 S )‐leukotrienes B 3 is reported which uses a flexible and convergent strategy. The key steps involve a Sonogashira coupling between the bromodienone 4 and the propargylic difluoride 5 ; this is followed by a CBS type reduction to establish the (12 R ) or (12 S ) stereocenters. A final semihydrogenation, under controlled conditions, affords the required E,E,Z trienic system. (© Wiley‐VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2005)" @default.
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- W2017859499 date "2005-08-15" @default.
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- W2017859499 title "Stereoselective Synthesis of the 5,5‐Difluoro‐(12<i>R</i>)‐ and ‐(12<i>S</i>)‐Leukotrienes B<sub>3</sub>" @default.
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- W2017859499 doi "https://doi.org/10.1002/ejoc.200500200" @default.
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