FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017876987> ?p ?o ?g. }

• W2017876987 endingPage "4142" @default.
• W2017876987 startingPage "4132" @default.
• W2017876987 abstract "Abstract An Erratum has been published for this article in J Polym Sci Part A: Polym Chem (2004) 42(19) 5030 . The addition of soluble quaternaryammonium halides (QX) in catalytic amounts takes into solution CuX/pentamethyldiethylenetriamine (PMDETA) complex (X = Cl, Br) in methyl methacrylate (MMA). The soluble catalyst complex provided much better control of the polymerization of MMA at ambient temperature than did the insoluble catalyst formed in the absence of QX, with CuCl/PMDETA/Aliquat® 336 (AQCl) proving to be superior to the CuBr/PMDETA/Bu 4 NBr catalyst system. The effect was independent of the size of the quaternaryammonium ion. Also, the presence of Cl in the catalyst–QX combination either as CuCl or as QCl was enough to give much better control than that provided by a wholly Br‐based system. Among the various initiators used, that is, ethyl 2‐bromoisobutyrate (EBiB), methyl 2‐bromopropionate (MBP), 1‐phenylethyl bromide (PEBr), and p ‐toluenesulfonyl chloride (pTsCl), only EBiB gave a satisfactory result. With MBP and PEBr the initiation was slower than the propagation, whereas with pTsCl the initiation was very fast, so that instantaneous termination occurred. The living nature of the polymers was shown by block copolymer preparation. It has been suggested that some of the added halide ions entered into the coordination spheres of Cu(I) and Cu(II), leading to their improved solubility and stronger deactivation by the Cu(II) complex. © 2004 Wiley Periodicals, Inc. J Polym Sci Part A: Polym Chem 42: 4132–4142, 2004" @default.
• W2017876987 created "2016-06-24" @default.
• W2017876987 creator A5008038061 @default.
• W2017876987 creator A5028058344 @default.
• W2017876987 creator A5070449895 @default.
• W2017876987 date "2004-07-19" @default.
• W2017876987 modified "2023-10-08" @default.
• W2017876987 title "Atom transfer radical polymerization of methyl methacrylate at ambient temperature using soluble Cu(I) complex catalysts formed with mixed ligands of multidentate amines and halide ions" @default.
• W2017876987 cites W1977844811 @default.
• W2017876987 cites W1979575631 @default.
• W2017876987 cites W1980337066 @default.
• W2017876987 cites W1989574700 @default.
• W2017876987 cites W1995709260 @default.
• W2017876987 cites W1996807119 @default.
• W2017876987 cites W1997365582 @default.
• W2017876987 cites W2004727795 @default.
• W2017876987 cites W2013065128 @default.
• W2017876987 cites W2022455682 @default.
• W2017876987 cites W2024764154 @default.
• W2017876987 cites W2025337427 @default.
• W2017876987 cites W2029958261 @default.
• W2017876987 cites W2030950757 @default.
• W2017876987 cites W2031077483 @default.
• W2017876987 cites W2033620725 @default.
• W2017876987 cites W2041225974 @default.
• W2017876987 cites W2042896841 @default.
• W2017876987 cites W2045055557 @default.
• W2017876987 cites W2048323452 @default.
• W2017876987 cites W2053726121 @default.
• W2017876987 cites W2055393399 @default.
• W2017876987 cites W2056201335 @default.
• W2017876987 cites W2060979151 @default.
• W2017876987 cites W2066093182 @default.
• W2017876987 cites W2074554162 @default.
• W2017876987 cites W2080837087 @default.
• W2017876987 cites W2082039918 @default.
• W2017876987 cites W2085739736 @default.
• W2017876987 cites W2088137724 @default.
• W2017876987 cites W2088862173 @default.
• W2017876987 cites W2088890545 @default.
• W2017876987 cites W2089023732 @default.
• W2017876987 cites W2089773460 @default.
• W2017876987 cites W2089792360 @default.
• W2017876987 cites W2090651235 @default.
• W2017876987 cites W2119452194 @default.
• W2017876987 cites W2132406399 @default.
• W2017876987 cites W2141158481 @default.
• W2017876987 cites W2148440516 @default.
• W2017876987 cites W2153925194 @default.
• W2017876987 cites W2317295301 @default.
• W2017876987 cites W2501841321 @default.
• W2017876987 cites W2523569737 @default.
• W2017876987 cites W4246326475 @default.
• W2017876987 doi "https://doi.org/10.1002/pola.20182" @default.
• W2017876987 hasPublicationYear "2004" @default.
• W2017876987 type Work @default.
• W2017876987 sameAs 2017876987 @default.
• W2017876987 citedByCount "32" @default.
• W2017876987 countsByYear W20178769872012 @default.
• W2017876987 countsByYear W20178769872013 @default.
• W2017876987 countsByYear W20178769872016 @default.
• W2017876987 countsByYear W20178769872018 @default.
• W2017876987 countsByYear W20178769872019 @default.
• W2017876987 countsByYear W20178769872021 @default.
• W2017876987 countsByYear W20178769872022 @default.
• W2017876987 crossrefType "journal-article" @default.
• W2017876987 hasAuthorship W2017876987A5008038061 @default.
• W2017876987 hasAuthorship W2017876987A5028058344 @default.
• W2017876987 hasAuthorship W2017876987A5070449895 @default.
• W2017876987 hasConcept C115624301 @default.
• W2017876987 hasConcept C150539798 @default.
• W2017876987 hasConcept C155647269 @default.
• W2017876987 hasConcept C15920480 @default.
• W2017876987 hasConcept C161790260 @default.
• W2017876987 hasConcept C171560689 @default.
• W2017876987 hasConcept C178516000 @default.
• W2017876987 hasConcept C178790620 @default.
• W2017876987 hasConcept C179104552 @default.
• W2017876987 hasConcept C185592680 @default.
• W2017876987 hasConcept C188027245 @default.
• W2017876987 hasConcept C2776300020 @default.
• W2017876987 hasConcept C2777935641 @default.
• W2017876987 hasConcept C2780073701 @default.
• W2017876987 hasConcept C44228677 @default.
• W2017876987 hasConcept C521977710 @default.
• W2017876987 hasConceptScore W2017876987C115624301 @default.
• W2017876987 hasConceptScore W2017876987C150539798 @default.
• W2017876987 hasConceptScore W2017876987C155647269 @default.
• W2017876987 hasConceptScore W2017876987C15920480 @default.
• W2017876987 hasConceptScore W2017876987C161790260 @default.
• W2017876987 hasConceptScore W2017876987C171560689 @default.
• W2017876987 hasConceptScore W2017876987C178516000 @default.
• W2017876987 hasConceptScore W2017876987C178790620 @default.
• W2017876987 hasConceptScore W2017876987C179104552 @default.
• W2017876987 hasConceptScore W2017876987C185592680 @default.
• W2017876987 hasConceptScore W2017876987C188027245 @default.
• W2017876987 hasConceptScore W2017876987C2776300020 @default.
• W2017876987 hasConceptScore W2017876987C2777935641 @default.

• next