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- W2017880162 abstract "Abstract The combination of zero‐valent iron (Fe(0) powder) and copper(II) bromide was used to mediate the polymerization of methyl methacrylate (MMA) or styrene (St) at 25 ° C. The results demonstrated that the solvent played an important role on the polymerization rate and molecular‐weight control. The polymerization in toluene displayed a poorly controlled process with remarkably low polymerization rate. With dimethyl sulfoxide (DMSO) as solvent, the polymerization proceeded in a relatively high rate, and the number‐average molecular weights were controlled especially at higher conversion. High conversions (80%) of St could be achieved with narrow molecular weight distributions in DMSO at 25 °C. It was supposed that Fe(0) played a dual role, the activator for the generation of active radical and the reducing agent for CuBr 2 ." @default.
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- W2017880162 date "2012-02-09" @default.
- W2017880162 modified "2023-10-10" @default.
- W2017880162 title "Fe(0) Powder/CuBr2-Mediated “Living”/Controlled Radical Polymerization of Methyl Methacrylate and Styrene at Ambient Temperature" @default.
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- W2017880162 doi "https://doi.org/10.1002/macp.201100545" @default.
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