FRINK Linked Data Fragments server

Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017885093> ?p ?o ?g. }

• W2017885093 endingPage "11323" @default.
• W2017885093 startingPage "11323" @default.
• W2017885093 abstract "We report detailed synthesis of a range of porous graphene oxide frameworks (GOFs) by expansion of graphene oxide (GO) sheets with various linear boronic acid pillaring units in a solvothermal reaction. The GOF structures develop through boronate-ester formation as a result of B–O bonding between boronic acids and oxygen functional groups on the GO layers. Synthesized GOFs exhibit periodic layered structures with largely expanded interlayer spacing as characterized by X-ray powder diffraction (XRD). The boronate-ester link formation is further evidenced by Fourier transform infrared (FTIR) and Raman spectroscopy. Furthermore, the strong boronate-ester bonds between GO layers results in improved thermal stability over the precursor GO. The solvent-free, evacuated frameworks provide highly increased accessible surface area for nitrogen adsorption compared to GO alone, which depends on the type and length of the boronic acid, indicating the importance of pillaring unit. Both isosteric heat of adsorption (Qst) and the adsorbed hydrogen capacity per surface area are twice as large as typical porous carbon materials and comparable to metal–organic frameworks (MOFs) with open metal centers. This enhanced Qst and adsorption capacity is attributed to optimum interlayer spacing between graphene planes such that hydrogen molecules interact with both surfaces. Finally, our systematic study reveals the profound effect of both synthesis and activation temperatures to obtain porous framework structures." @default.
• W2017885093 created "2016-06-24" @default.
• W2017885093 creator A5069576290 @default.
• W2017885093 creator A5070996452 @default.
• W2017885093 creator A5077586408 @default.
• W2017885093 creator A5083901497 @default.
• W2017885093 date "2011-01-01" @default.
• W2017885093 modified "2023-09-25" @default.
• W2017885093 title "Porous graphene oxide frameworks: Synthesis and gas sorption properties" @default.
• W2017885093 cites W113299661 @default.
• W2017885093 cites W1964718824 @default.
• W2017885093 cites W1971745686 @default.
• W2017885093 cites W1975175823 @default.
• W2017885093 cites W1976156302 @default.
• W2017885093 cites W1980510962 @default.
• W2017885093 cites W1991482062 @default.
• W2017885093 cites W1999023472 @default.
• W2017885093 cites W2001816390 @default.
• W2017885093 cites W2003370141 @default.
• W2017885093 cites W2025570578 @default.
• W2017885093 cites W2025841376 @default.
• W2017885093 cites W2036939243 @default.
• W2017885093 cites W2040935338 @default.
• W2017885093 cites W2043875220 @default.
• W2017885093 cites W2048046484 @default.
• W2017885093 cites W2049145344 @default.
• W2017885093 cites W2052702569 @default.
• W2017885093 cites W2065373266 @default.
• W2017885093 cites W2079572507 @default.
• W2017885093 cites W2080429874 @default.
• W2017885093 cites W2109807803 @default.
• W2017885093 cites W2132214742 @default.
• W2017885093 cites W2135479172 @default.
• W2017885093 cites W2141235778 @default.
• W2017885093 cites W2141237492 @default.
• W2017885093 cites W2151693477 @default.
• W2017885093 cites W2154198958 @default.
• W2017885093 cites W2158168036 @default.
• W2017885093 cites W2161947509 @default.
• W2017885093 cites W2170095967 @default.
• W2017885093 doi "https://doi.org/10.1039/c1jm11699a" @default.
• W2017885093 hasPublicationYear "2011" @default.
• W2017885093 type Work @default.
• W2017885093 sameAs 2017885093 @default.
• W2017885093 citedByCount "203" @default.
• W2017885093 countsByYear W20178850932012 @default.
• W2017885093 countsByYear W20178850932013 @default.
• W2017885093 countsByYear W20178850932014 @default.
• W2017885093 countsByYear W20178850932015 @default.
• W2017885093 countsByYear W20178850932016 @default.
• W2017885093 countsByYear W20178850932017 @default.
• W2017885093 countsByYear W20178850932018 @default.
• W2017885093 countsByYear W20178850932019 @default.
• W2017885093 countsByYear W20178850932020 @default.
• W2017885093 countsByYear W20178850932021 @default.
• W2017885093 countsByYear W20178850932022 @default.
• W2017885093 countsByYear W20178850932023 @default.
• W2017885093 crossrefType "journal-article" @default.
• W2017885093 hasAuthorship W2017885093A5069576290 @default.
• W2017885093 hasAuthorship W2017885093A5070996452 @default.
• W2017885093 hasAuthorship W2017885093A5077586408 @default.
• W2017885093 hasAuthorship W2017885093A5083901497 @default.
• W2017885093 hasConcept C105569014 @default.
• W2017885093 hasConcept C127413603 @default.
• W2017885093 hasConcept C150394285 @default.
• W2017885093 hasConcept C159985019 @default.
• W2017885093 hasConcept C171250308 @default.
• W2017885093 hasConcept C178790620 @default.
• W2017885093 hasConcept C185592680 @default.
• W2017885093 hasConcept C191897082 @default.
• W2017885093 hasConcept C192562407 @default.
• W2017885093 hasConcept C2779851234 @default.
• W2017885093 hasConcept C30080830 @default.
• W2017885093 hasConcept C42360764 @default.
• W2017885093 hasConcept C58445606 @default.
• W2017885093 hasConcept C6648577 @default.
• W2017885093 hasConceptScore W2017885093C105569014 @default.
• W2017885093 hasConceptScore W2017885093C127413603 @default.
• W2017885093 hasConceptScore W2017885093C150394285 @default.
• W2017885093 hasConceptScore W2017885093C159985019 @default.
• W2017885093 hasConceptScore W2017885093C171250308 @default.
• W2017885093 hasConceptScore W2017885093C178790620 @default.
• W2017885093 hasConceptScore W2017885093C185592680 @default.
• W2017885093 hasConceptScore W2017885093C191897082 @default.
• W2017885093 hasConceptScore W2017885093C192562407 @default.
• W2017885093 hasConceptScore W2017885093C2779851234 @default.
• W2017885093 hasConceptScore W2017885093C30080830 @default.
• W2017885093 hasConceptScore W2017885093C42360764 @default.
• W2017885093 hasConceptScore W2017885093C58445606 @default.
• W2017885093 hasConceptScore W2017885093C6648577 @default.
• W2017885093 hasIssue "30" @default.
• W2017885093 hasLocation W20178850931 @default.
• W2017885093 hasOpenAccess W2017885093 @default.
• W2017885093 hasPrimaryLocation W20178850931 @default.
• W2017885093 hasRelatedWork W2020946050 @default.
• W2017885093 hasRelatedWork W2054558880 @default.
• W2017885093 hasRelatedWork W2134948224 @default.
• W2017885093 hasRelatedWork W2137163290 @default.

• next