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- W2017910274 abstract "In the presence of chiral Lewis base catalysts [(S)-BINAPO or (R,R)-DIOPO] and trichlorosilane as the reducing agent, α,β-unsaturated ketones undergo 1,4-reduction and subsequent aldol reaction with aldehydes smoothly and with excellent stereoselectivity (dr up to 99:1 and er up to 99:1). Because 1,2- and 1,4-reductions of α,β-unsaturated aldehydes scarcely happen under these conditions, enals are well tolerated as aldol partners keeping the C=C bond intact." @default.
- W2017910274 created "2016-06-24" @default.
- W2017910274 date "2010-03-22" @default.
- W2017910274 modified "2023-09-26" @default.
- W2017910274 title "Chiral Base-Catalyzed Reductive Aldol Reaction with Trichlorosilane" @default.
- W2017910274 doi "https://doi.org/10.1055/s-0029-1219511" @default.
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