Matches in SemOpenAlex for { <https://semopenalex.org/work/W2017911892> ?p ?o ?g. }
- W2017911892 endingPage "84" @default.
- W2017911892 startingPage "73" @default.
- W2017911892 abstract "Hexagonally packed mesostructured titanosilicates of the SBA-15 type have been prepared in moderately acidic aqueous media starting from sodium disilicate Na2Si2O5, TiOSO4, and olefin oxide co-polymer of the Pluronic type (P123) as a template. Structure–texture parameters of the synthesised materials were characterised by using X-ray diffraction and nitrogen adsorption techniques. The titanium state in the silicate matrix was characterised by DR-UV, IR, Raman spectroscopy, and XPS. The catalytic properties of the new titaniumsilicates were tested in oxidation reactions with aqueous H2O2 using methyl phenyl sulfide and 2,3,6-trimethylphenol as model substrates and compared with the catalytic properties of TS-1 and Ti-MMM (titaniumsilicate of the MCM-41 type). The structure of the Ti-SBA-15 materials, by contrast to Ti-MMM catalysts, was proved to be hydrolytically stable towards aqueous H2O2. The catalytic activity of Ti-SBA-15 is considerably lower than that of Ti-MMM, most likely due to a lower titanium dispersion and higher wall thickness of the former material, which makes part of titanium sites unavailable for the reactants." @default.
- W2017911892 created "2016-06-24" @default.
- W2017911892 creator A5000468650 @default.
- W2017911892 creator A5005264267 @default.
- W2017911892 creator A5013657391 @default.
- W2017911892 creator A5031214278 @default.
- W2017911892 creator A5033207014 @default.
- W2017911892 creator A5054012694 @default.
- W2017911892 creator A5060459445 @default.
- W2017911892 creator A5075650763 @default.
- W2017911892 creator A5078309403 @default.
- W2017911892 date "2003-05-01" @default.
- W2017911892 modified "2023-09-25" @default.
- W2017911892 title "H2O2-based selective oxidations over titaniumsilicates of SBA-15 type" @default.
- W2017911892 cites W1965092763 @default.
- W2017911892 cites W1969423167 @default.
- W2017911892 cites W1970476050 @default.
- W2017911892 cites W1972586528 @default.
- W2017911892 cites W1975563471 @default.
- W2017911892 cites W1978549880 @default.
- W2017911892 cites W1979337448 @default.
- W2017911892 cites W1980379757 @default.
- W2017911892 cites W1980978977 @default.
- W2017911892 cites W1981554179 @default.
- W2017911892 cites W1982175365 @default.
- W2017911892 cites W1983544506 @default.
- W2017911892 cites W1992739209 @default.
- W2017911892 cites W1994582943 @default.
- W2017911892 cites W1995041236 @default.
- W2017911892 cites W1997693922 @default.
- W2017911892 cites W1998566252 @default.
- W2017911892 cites W1999310410 @default.
- W2017911892 cites W1999616105 @default.
- W2017911892 cites W2004962137 @default.
- W2017911892 cites W2009493749 @default.
- W2017911892 cites W2013496310 @default.
- W2017911892 cites W2017063205 @default.
- W2017911892 cites W2018685468 @default.
- W2017911892 cites W2023691462 @default.
- W2017911892 cites W2024663420 @default.
- W2017911892 cites W2029276049 @default.
- W2017911892 cites W2030046405 @default.
- W2017911892 cites W2033455879 @default.
- W2017911892 cites W2034622943 @default.
- W2017911892 cites W2039241045 @default.
- W2017911892 cites W2039855563 @default.
- W2017911892 cites W2048263534 @default.
- W2017911892 cites W2054111649 @default.
- W2017911892 cites W2057325762 @default.
- W2017911892 cites W2067413963 @default.
- W2017911892 cites W2071204487 @default.
- W2017911892 cites W2072642581 @default.
- W2017911892 cites W2075625422 @default.
- W2017911892 cites W2075802779 @default.
- W2017911892 cites W2078019061 @default.
- W2017911892 cites W2079145727 @default.
- W2017911892 cites W2082662063 @default.
- W2017911892 cites W2099012186 @default.
- W2017911892 cites W2135016620 @default.
- W2017911892 cites W2135820848 @default.
- W2017911892 cites W309390145 @default.
- W2017911892 cites W4244985746 @default.
- W2017911892 cites W91858662 @default.
- W2017911892 doi "https://doi.org/10.1016/s1387-1811(03)00287-7" @default.
- W2017911892 hasPublicationYear "2003" @default.
- W2017911892 type Work @default.
- W2017911892 sameAs 2017911892 @default.
- W2017911892 citedByCount "58" @default.
- W2017911892 countsByYear W20179118922012 @default.
- W2017911892 countsByYear W20179118922013 @default.
- W2017911892 countsByYear W20179118922014 @default.
- W2017911892 countsByYear W20179118922015 @default.
- W2017911892 countsByYear W20179118922016 @default.
- W2017911892 countsByYear W20179118922017 @default.
- W2017911892 countsByYear W20179118922018 @default.
- W2017911892 countsByYear W20179118922021 @default.
- W2017911892 countsByYear W20179118922023 @default.
- W2017911892 crossrefType "journal-article" @default.
- W2017911892 hasAuthorship W2017911892A5000468650 @default.
- W2017911892 hasAuthorship W2017911892A5005264267 @default.
- W2017911892 hasAuthorship W2017911892A5013657391 @default.
- W2017911892 hasAuthorship W2017911892A5031214278 @default.
- W2017911892 hasAuthorship W2017911892A5033207014 @default.
- W2017911892 hasAuthorship W2017911892A5054012694 @default.
- W2017911892 hasAuthorship W2017911892A5060459445 @default.
- W2017911892 hasAuthorship W2017911892A5075650763 @default.
- W2017911892 hasAuthorship W2017911892A5078309403 @default.
- W2017911892 hasConcept C120665830 @default.
- W2017911892 hasConcept C121332964 @default.
- W2017911892 hasConcept C127413603 @default.
- W2017911892 hasConcept C150394285 @default.
- W2017911892 hasConcept C161790260 @default.
- W2017911892 hasConcept C175708663 @default.
- W2017911892 hasConcept C178790620 @default.
- W2017911892 hasConcept C179104552 @default.
- W2017911892 hasConcept C184651966 @default.
- W2017911892 hasConcept C185592680 @default.
- W2017911892 hasConcept C192562407 @default.