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• W2017924297 abstract "The growth of Pt−Rh alloy crystallites vacuum-deposited on α-Al2O3 substrates by thermal treatment was investigated by atomic force microscopy (AFM) as a function of Rh concentrations. As-deposited Pt thin film without any Rh concentration changed into Pt crystallites dispersed on the substrate by annealing at 800 °C in oxidative and reductive atmospheres. The oxidative atmosphere remarkably enhanced the growth of Pt crystallites, while it is not the case in the growth of pure Rh crystallites. However, when Rh was added to Pt, the crystallites remained very small and highly dispersed on the substrates even after the annealing at 800 °C in an oxidative atmosphere. We also investigated the surface concentration of Pt and Rh by Rutherford backscattering spectroscopy (RBS) and discussed the effect of wettability of Rh oxide as a key role in inhibiting the growth of Pt−Rh crystallites." @default.
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• W2017924297 date "1998-03-01" @default.
• W2017924297 modified "2023-10-18" @default.
• W2017924297 title "Growth of Pt−Rh Alloy Crystallites on α-Al₂O₃ Studied by Atomic Force Microscopy and Rutherford Backscattering Spectroscopy" @default.
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• W2017924297 doi "https://doi.org/10.1021/jp973409s" @default.
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