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• W2017993178 abstract "The oxidation of tartronate and mesoxalate ion by permanganate has been studied in 0.1–2.0 M aqueous NaOH. Manganate(VI) ion is formed in the first rapid phase, which is kinetically first order with respect to both MnO4− and the substrate. The second-order rate constant depends on the OH− ion concentration, which implies higher reactivity of the species with deprotonated 2-hydroxy groups. The proposed mechanism consists of outer sphere electron transfer to the MnO4− ion, generating an anion-radical and manganate(VI). The latter reacts with both substrates in the second, slower phase, affording manganate(V) as a relatively stable product in strong alkali. The anion-radical is oxidized by MnO4− in a rapid step." @default.
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• W2017993178 date "1991-08-01" @default.
• W2017993178 modified "2023-10-18" @default.
• W2017993178 title "Formation of manganate(V) in oxidations by permanganate ion in strongly alkaline solutions" @default.
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• W2017993178 doi "https://doi.org/10.1016/s0020-1693(00)87927-x" @default.
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