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- W2017998516 abstract "Relative hydrolysis rates were determined for a series of 14 nitrosubstituted esters and some comparison compounds in 75/25 acetonitrile/water at 75.3°C. The nitroalkyl esters were found to undergo unexpectedly rapid hydrolysis relative to other negatively substituted alkyl esters such as fluoroalkyl. To explain this result, participation of the nitro group in the hydrolysis, especially in the case of trinitromethyl compounds, is postulated. Nitro groups in the acid portion of the ester molecule can increase or decrease the reactivtiy towards hydrolysis, depending on the site of substitution." @default.
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- W2017998516 date "1987-12-01" @default.
- W2017998516 modified "2023-09-26" @default.
- W2017998516 title "Relative rates of Hydrolysis of Nitro- and Fluoro-Substituted Esters" @default.
- W2017998516 doi "https://doi.org/10.1002/prep.19870120605" @default.
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