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• W2018009675 abstract "The high temperature form of silver tungstate, Ag8W4O16, contains tetratungstate ions in which the tungsten atoms are coplanar and each is octahedrally coordinated to oxygen atoms. Two octahedra share three edges with other octahedra and two octahedra share two edges with other octahedra. Four types of coordination for the Ag+ ion are found in the structure: distorted triangular prismatic (with an additional more distant oxygen through a quadrilateral face), octahedral, tetrahedral, and twofold linear. These have been observed before in different crystals, but not all in the same crystal. The deviation from centrosymmetry of the polyion appears to be highly stable as deduced from unsuccessful attempts to reverse the polarization of the crystal. Crystals of Ag8W4O16 are orthorhombic, belong to space group Pn2n (C102v) with lattice constants a=10.89, b=12.03, c=5.92Å all ±0.02Å and contain 2 Ag8W4O16 per unit cell. X-ray diffraction data obtained with a Buerger-Supper single crystal automatic diffractometer were used to determine the crystal structure." @default.
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• W2018009675 date "1975-08-01" @default.
• W2018009675 modified "2023-10-04" @default.
• W2018009675 title "(W4O16)8− Polyion in the high temperature modification of silver tungstate" @default.
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• W2018009675 doi "https://doi.org/10.1016/0025-5408(75)90193-2" @default.
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