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• W2018025908 abstract "Polystyrene functionalized SWCNTs, prepared by copper(I) catalyzed click coupling of alkyne-decorated SWCNTs with well-defined, azide-terminated polystyrene, were transformed to water-soluble structures through sulfonation of the grafted polystyrene chains. The degree of polystyrene sulfonation was varied from 20 to 34 mol%, and was found to be directly proportional to the aqueous solubility of the material. The resulting sulfonated polystyrene-functionalized SWCNTs (SPS-SWCNTs) were found to be pH responsive, forming homogeneous solutions in water at pH values between 3 and 13. Outside of this pH range, the SPS-SWCNTs rapidly precipitate from solution. In addition, it was found that nanotube aggregation could be significantly reduced at high pH, where the sulfonate groups led to electrostatic repulsion between nanotubes." @default.
• W2018025908 created "2016-06-24" @default.
• W2018025908 creator A5001536268 @default.
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• W2018025908 date "2007-04-01" @default.
• W2018025908 modified "2023-10-14" @default.
• W2018025908 title "Water-soluble SWCNTs from sulfonation of nanotube-bound polystyrene" @default.
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• W2018025908 doi "https://doi.org/10.1016/j.carbon.2006.12.022" @default.
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