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- W2018035118 abstract "Abstract Bromine oxidation of [ReBr(CO)3(PR3)2] [PR3 = PMe2Ph, PEt2Ph, PMePh2, PPh3, PPh2C6H4Me-4 or P(C6H4OMe-4)3] yields stable seven-coordinate rhenium(III) complexes [ReBr3(CO)2(PR3)2] only for the less sterically demanding phosphines PMe2Ph, PEt2Ph and PMePh2. Crystals of [ReBr3(CO)2(PMe2Ph)2] (1) are triclinic, space group P 1 − , Z = 2, in a unit cell with lattice parameters a = 9.575(8), b = 14.705(11), c = 9.629(12) A, α = 77.71(7), β = 109.06(8) and γ = 115.02(8)°. 2991 independent reflections above background were collected on a diffractometer and refined to R0.07. The metal atom has a capped octahedral environment with a carbonyl in the unique capping position [1.87(3) A], two phosphines [2.456(13), 2.496(11) A] and one carbonyl 1.85(5) A in the capped face, and three bromine atoms in the uncapped face [2.589(5), 2.623(6), 2.622(5) A]. Attempts to convert (1) to the six-coordinate d4 cation [ReBr2(CO)2(PMe2Ph)2]+ for structural comparison with the isoelectronic Group 6 analogues [MBr2(CO)2(PR3)2] (M = Mo or W) were unsuccessful." @default.
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- W2018035118 date "1984-01-01" @default.
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- W2018035118 title "Phosphine containing rhenium(III) carbonyl complexes. The crystal and molecular structure of tribromodicarbonylbis(dimethyl-phenylphosphine)rhenium(III)" @default.
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