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- W2018043237 abstract "An empirical relationship was derived which relates properties of the mobile phase modifier to the chiral selectivity factor for a given analyte/chiral selector combination. Using carbon dioxide and heptane-based mobile phases, the effect of various mobile phase modifiers on Pirkle-type stationary phases may be accurately modeled using a two-parameter equation. Similar results are obtained using cellulosic stationary phases with carbon dioxide-based mobile phases. Modeling separations performed using heptane-based mobile phases with cellulosic stationary phases were not successful. The predictive ability of this modeling approach was demonstrated using novel modifiers and chiral analytes." @default.
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- W2018043237 title "Empirical relationship between chiral selectivity and mobile phase modifier properties" @default.
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- W2018043237 doi "https://doi.org/10.1016/s0021-9673(99)00637-8" @default.
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