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- W2018043958 abstract "A magic-angle spinning (MAS) 2H NMR experiment was applied to study the molecular motion in paramagnetic compounds. The temperature dependences of 2H MAS NMR spectra were measured for paramagnetic [M(H2O)6][SiF6] (M = Ni2+, Mn2+, Co2+) and diamagnetic [Zn(H2O)6][SiF6]. The paramagnetic compounds exhibited an asymmetric line shape in 2H MAS NMR spectra because of the electron−nuclear dipolar coupling. The drastic changes in the shape of spinning sideband patterns and in the line width of spinning sidebands due to the 180° flip of water molecules and the reorientation of [M(H2O)6]2+ about its C3 axis were observed. In the paramagnetic compounds, paramagnetic spin−spin relaxation and anisotropic g-factor result in additional linebroadening of each of the spinning sidebands. The spectral simulation of MAS 2H NMR, including the effects of paramagnetic shift and anisotropic spin−spin relaxation due to electron−nuclear dipolar coupling and anisotropic g-factor, was performed for several molecular motions. Information about molecular motions in the dynamic range of 102 s-1 ≤ k ≤ 108 s-1 can be obtained for the paramagnetic compounds from the analysis of 2H MAS NMR spectra when these paramagnetic effects are taken into account." @default.
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- W2018043958 date "2007-11-21" @default.
- W2018043958 modified "2023-09-26" @default.
- W2018043958 title "Molecular Dynamics in Paramagnetic Materials as Studied by Magic-Angle Spinning <sup>2</sup>H NMR Spectra" @default.
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- W2018043958 doi "https://doi.org/10.1021/jp075405l" @default.
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