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- W2018056687 abstract "The formation of formate species on a K-Os/Al2O3 catalyst was followed by IR spectroscopy, and the reactivity of the surface formate in H2 and water atmospheres was studied. The results strongly suggest that the formate is an intermediate in the water-gas shift reaction. A catalytic cycle is postulated in which bicarbonate, formate and hydroxyl surface species are involved. The formation of the formate from CO by reaction with OH− is presumably the slowest step in the cycle." @default.
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- W2018056687 date "1989-06-01" @default.
- W2018056687 modified "2023-09-23" @default.
- W2018056687 title "Formation and reactivities of formate species on a potassium-modified osmium/alumina catalyst: an infrared spectroscopic study" @default.
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- W2018056687 doi "https://doi.org/10.1016/0304-5102(89)80085-9" @default.
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