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- W2018064983 abstract "Two novel cobalt(II) coordination polymers [Co2(H2O)4(Hbidc)2]n (1) and [Co(Hbidc)]n (2), (Hbidc = 1H-benzimidazole-5,6-dicarboxylate) were synthesized hydrothermally by treating CoSO4 and H3bidc at 160 or 220 °C, respectively. X-Ray diffraction analyses showed that compound 1 is a 1-D chain polymer with dimer units [Co2(H2O)4(Hbidc)2] and the infinite chains of compound 1 array uniformly towards the crystallographic a-axis in a 3-D supramolecular framework which possesses abundant hydrogen-bonding interactions between uncoordinated carboxylo-oxygen atoms and coordinated water molecules or N–H groups in imidazole rings. Compound 2 is a novel five-coordinated cobalt(II) chain compound exhibiting a 2-D polymeric network with parallel zip-like cobalt–carboxylate chains along the crystallographic b-axis and the 2-D polymeric networks of compound 2 exhibit a layered arrangement, in which the strong hydrogen-bonding interaction between uncoordinated carboxylo-oxygen atoms and N–H groups in the imidazole rings play a key role in the final 3-D supramolecular architectures. Magnetic studies revealed that compound 1 shows a ferromagnetic coupling between two CoII ions in the dimer unit and compound 2 exhibits an antiferromagnetic property." @default.
- W2018064983 created "2016-06-24" @default.
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- W2018064983 date "2009-01-01" @default.
- W2018064983 modified "2023-10-09" @default.
- W2018064983 title "Two cobalt(II) coordination polymers [Co2(H2O)4(Hbidc)2]n and [Co(Hbidc)]n (Hbidc = 1H-benzimidazole-5,6-dicarboxylate): syntheses, crystal structures, and magnetic properties" @default.
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- W2018064983 doi "https://doi.org/10.1039/b815464c" @default.
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