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- W2018077125 abstract "Pt(100) and (111) single-crystal surfaces containing adsorbed iodine were characterized by a combination of electron techniques in ultra-high vacuum (UHV) and electrochemical methods in aqueous solution. The low-energy electron diffraction (l.e.e.d.) patterns varied with coverage, indicating long range order of the overlayer and occasional registry with the substrate. The observed structures were hexagonal, exhibiting distortion in some cases. Quantitative Auger electron spectroscopy (a.e.s.) corroborated the iodine coverages inferred from l.e.e.d. Thermal desorption mass spectrometry (t.d.m.s.) revealed maxima in the iodine desorption rate from the (100) surface near 600 and 900 K, corresponding to specific surface structures, with a broad continuum in between; only a continuum was produced by Pt(111) surfaces. Atomic iodine is the predominant thermal desorption product. Electrochemical current-potential curves obtained by linear scan voltammetry in aqueous acid of ordered layers produced in UHV differ markedly for different faces and from those for adsorbed layers produced on the same substrates from aqueous solutions. Integration of voltammetric curves (coulometry) verified, for iodine overlayers, the effectiveness of a.e.s. for quantitative analysis of an adsorbed monolayer." @default.
- W2018077125 created "2016-06-24" @default.
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- W2018077125 date "1979-06-01" @default.
- W2018077125 modified "2023-10-11" @default.
- W2018077125 title "L.e.e.d. and electrochemistry of iodine on Pt(100) and Pt(111) single-crystal surfaces" @default.
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- W2018077125 doi "https://doi.org/10.1016/s0022-0728(79)80179-5" @default.
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