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- W2018077324 abstract "[reaction: see text] Asymmetric surrogate glycolate alkylation has been performed under phase-transfer conditions. Diphenylmethyloxy-2,5-dimethoxyacetophenone with trifluorobenzyl cinchonidinium catalyst and cesium hydroxide provided alkylation products at -35 degrees C in high yield (80-99%) and with excellent enantioselectivities (90:10 to 95:5). Useful alpha-hydroxy products were obtained using bis-TMS peroxide Baeyer-Villiger conditions and selective transesterification. The intermediate aryl ester can be obtained with >99% ee after a single recrystallization. A tight ion-pair model for the observed (S)-stereoinduction is proposed." @default.
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- W2018077324 date "2004-10-19" @default.
- W2018077324 modified "2023-09-23" @default.
- W2018077324 title "Phase-Transfer-Catalyzed Asymmetric Glycolate Alkylation." @default.
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- W2018077324 doi "https://doi.org/10.1002/chin.200442026" @default.
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