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- W2018085128 abstract "The electroreduction of cobalt (II) from solutions containing pyridine was investigated with stationary electrode polarography at a hanging mercury drop electrode using both single-scan and cyclic experiments. Scan rates ranged from 50 mVsec to 110 Vsec, and from the variation of the peak potential and the peak current function, ip/Vv, (where ip is the peak current, and v the rate of voltage scan) with scan rate, the reduction appeared to involve a reversible charge transfer followed by an extremely rapid chemical reaction in the amalgam to form a species not electroactive in the same potential range. This product appears to be a dimer or higher cobalt aggregate dissolved in the mercury. It is reoxidized at a potential about 1 V anodic of the reduction wave. This irreversible anodic wave was made the basis of a stripping analysis procedure for the determination of trace quantities of cobalt." @default.
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- W2018085128 date "1966-11-01" @default.
- W2018085128 modified "2023-09-25" @default.
- W2018085128 title "Electroanalytical study of the cobalt(II) pyridine—cobalt amalgam system, with application to stripping analysis" @default.
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- W2018085128 doi "https://doi.org/10.1016/0022-0728(66)80119-5" @default.
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