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- W2018085252 abstract "The emission spectra of single crystal Ba[Pt(CN)4]·4H2O were measured from 0 to 23 kbar for the two electronic transitions which are polarized with E‖c and E⊥;c. They exhibit a red-shift of −280 cm−1/kbar and −195 cm−1/kbar, respectively. 3he red-shift is explained by a pressure induced reduction of the intermolecular separation R in the direction of the linear chain (c-axis). The emission energies obtained at different pressures are compared with the results under normal conditions for various Me[Pt(CN)4]·xH2O salts (with different R). The close analogy between these two methods of R-reduction supports the importance of one-dimensional interaction for the interpretation of electronic properties of the tetracyano-platinates. Ba[Pt(CN)4]·4H2O shows a structural transition region in the pressure range studied here." @default.
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- W2018085252 date "1976-06-01" @default.
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- W2018085252 title "Polarized emission from Ba[Pt(CN)4]·4H2O single crystals under high pressure" @default.
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- W2018085252 doi "https://doi.org/10.1016/0009-2614(76)85111-1" @default.
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