Matches in SemOpenAlex for { <https://semopenalex.org/work/W2018088076> ?p ?o ?g. }
- W2018088076 endingPage "1431" @default.
- W2018088076 startingPage "1413" @default.
- W2018088076 abstract "Recent progress in the gas-phase activation of methane is discussed. We demonstrate that cluster size, charge state, and ligands crucially affect both the reactivity and selectivity of metal-mediated bond activation processes. We outline the important role that relativistic effects and spin densities play and discuss the paradigm of two-state reactivity in thermal reactions. State-of-the-art mass-spectrometry based experiments, in conjunction with electronic structure calculations, permit identification of the elementary steps at a strictly molecular level and thus allow to uncover mechanistic features for four types of reactions: (i) metal-mediated dehydrogenation of methane, (ii) ligand-switch processes of the type ML + CH4 → M(CH3) + HL, (iii) hydrogen-atom abstraction as the crucial step in the oxidative coupling of methane, and (iv) the mechanism of the challenging CH4→CH3OH conversion." @default.
- W2018088076 created "2016-06-24" @default.
- W2018088076 creator A5059088310 @default.
- W2018088076 date "2014-07-22" @default.
- W2018088076 modified "2023-10-01" @default.
- W2018088076 title "How and Why Do Cluster Size, Charge State, and Ligands Affect the Course of Metal-Mediated Gas-Phase Activation of Methane?" @default.
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