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- W2018117265 abstract "The activity of a number of ring alkyl-substituted phenols in the direct hydrodeoxygenation reaction (i.e. C-O bond scission without prior ring hydrogenation) in the presence of a commercial Co-Mo-Al2O3 catalyst has been investigated. The results indicate that the catalytically active site is stereochemically demanding. It is proposed that the phenol ring hydrogenation and the direct hydrodeoxygenation reaction proceed on the same catalytic site. The ease of the direct hydrodeoxygenation reaction is retarded mainly when transfer of the substrate hydroxyl group onto a co-ordinatively unsaturated metal site on the catalyst is inhibited. This occurs when the catalyst hydroxyl group receptor site is occupied by a co-ordinating ligand (poison) or when substituents on the substrate direct the phenolic hydroxyl group away from this metal site. The catalytic behaviour of Co-Mo-Al2O3 can be ‘transformed’ to resemble more closely that of Ni-Mo-Al2O3 (high reductive capacity) when the reaction medium contains both excess H2S and a co-ordinating ligand. It is proposed that this ‘transformed’ species is of importance in hydrodenitrogenation reactions in an H2S-rich environment." @default.
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- W2018117265 date "1982-10-01" @default.
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- W2018117265 title "Behaviour of Co-Mo-Al2O3 catalysts in the hydrodeoxygenation of phenols☆" @default.
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- W2018117265 doi "https://doi.org/10.1016/0016-2361(82)90104-1" @default.
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