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- W2018123456 abstract "Calcium sulfite was found to be sufficiently soluble in seawater of various compositions to allow the use of SO 2 for pretreatment of seawater (to prevent corrosion and alkaline scale formation) in desalting plants. The solubility of calcium sulfite, prepared by mixing 0.4M solutions of Na 2 SO 3 and CaCl 2 , in natural or synthetic seawater decreases with time and does not reach equilibrium for several weeks. Transient mmolal solubilities, at 25°C after 20 min and 24 h respectively, are 2.9 and 2.2 in natural seawater, 3.9 and 3.4 in 0.7M NaCl solution. This decrease is due to a gradual transformation, by a slow dissolution-recrystallization process, of a meta-stable phase of crystalline calcium sulfite into a more stable, less soluble, modification observed by X-ray crystallography, scanning electron microscopy and thermal analysis. The addition of Na 2 SO 3 to natural seawater produced solutions strongly supersaturated with respect to calcium sulfite. These remained stable for extended periods, and were only slowly affected by solid calcium sulfite added later." @default.
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- W2018123456 date "1982-05-01" @default.
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- W2018123456 title "Studies on alkaline earth sulfites — III [1]. Transient solubilities and phase changes of calcium sulfite in seawater" @default.
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