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- W2018134921 abstract "The ion-trap mass spectrometer has several features which make it a useful device for the study of ion/molecule reactions, viz., the ability to store ions for long periods, mass-selective storage, access to time and pressure-resolved data, and MS/MS capabilities in which the fragmentation behavior of selected ions may give insight into ion structure. These capabilities are used to study the gas-phase halomethylation of a variety of organic compounds with CH2Cl+ as the reagent ion. The ion/molecule reaction of greatest interest involves addition of CH2Cl+, followed by the elimination of HCl, resulting in a net addition of methyne. This methyne-addition reaction is observed in many aromatic compounds as well as such compounds as cycloheptatriene and cyclo-octene. The structures of the product ions were probed using collision-activated dissociation." @default.
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- W2018134921 date "1988-01-01" @default.
- W2018134921 modified "2023-10-12" @default.
- W2018134921 title "Ion/molecule reactions investigated by using tandem mass spectrometry in an ion trap: halomethylation" @default.
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- W2018134921 doi "https://doi.org/10.1016/s0003-2670(00)80846-6" @default.
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