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- W2018137948 abstract "Abstract Pulse radiolysis studies of the reduction of 6-hydroxy-5-nitrothymine (TNO 2 ) in neutral and acid aqueous solution have been carried out. Rate constants for the attack on TNO 2 by e - aq and CO 2 were found to be (2±0.1) × 10 10 and (1.7±0.2) × 10 8 M -1 s -1 , respectively. For the dissociated analog T(-H + )NO 2 the rate constants are (1.4±0.1) × 10 10 and (0.9±0.2) × 10 8 M -1 s -1 , respectively. Steady state experiments show a pH dependent formation of nitrite ions. The results are interpreted in terms of a reaction scheme involving three protolytic equilibria." @default.
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- W2018137948 title "A pulse-radiolysis study of the reduction of 6-hydroxy-5-nitrothymine in acid aqueous solutions" @default.
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- W2018137948 doi "https://doi.org/10.1016/0146-5724(80)90018-7" @default.
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