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- W2018138959 abstract "Durch Umsetzung von Tl2O3 und Cu2O im verschweißten Kupfertiegel gelang die Darstellung von TlCu[CuO2]; die Verbindung kristallisiert orthorhombisch innenzentriert in einem neuen Strukturtyp, Raumgruppe Imma (Nr. 74), mit den Gitterkonstanten a = 552,5 pm, b = 605,2 pm, c = 896,4 pm. Der Madelunganteil der Gitterenergie, MAPLE, sowie Effektive Koordinationszahlen, ECoN, diese über Mittlere Effektive Ionenradien, MEFIR, wurden berechnet. Preparation and Crystal Structure of TlCu[CuO2] By reaction of Tl2O3 and Cu2O in a sealed copper-type TlCu[CuO2] was synthesized; the orthorhombically bodycentered crystallizing compound forms a new structure type, space group Imma (no. 74), with the lattice constants a = 552.5 pm, b = 605.2 pm, c = 896.4 pm. The Madelung Part of Lattice Energy, MAPLE, as well as Effective Coordination Numbers, ECoN, these via Mean Effective Ionic Radii, MEFIR, were calculated." @default.
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- W2018138959 date "1991-11-01" @default.
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- W2018138959 title "Darstellung und Kristallstruktur von TICu[CuO2]" @default.
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- W2018138959 doi "https://doi.org/10.1002/zaac.19916050119" @default.
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