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- W2018148366 abstract "Nominally undoped zinc-blende polytype 3C-SiC single crystals have been studied by conventional electron-spin resonance (ESR), by the magnetic circular dichroism (MCD) absorption technique, and by optically detected ESR via the MCD (MCD-ESR). Apart from the dominant ESR signal ascribed to residual boron acceptors, an anisotropic spectrum with many lines is observed near liquid-He temperatures. It collapses into a hyperfine octet for Hensuremath{parallel}[111]. This spectrum is identified as the anisotropic $^{2}$E ground-state resonance of ${mathrm{V}}^{4+}$(3${mathit{d}}^{1}$) on the cubic Si site in 3C-SiC. Above 15 K this spectrum disappears and an isotropic hyperfine octet appears. It is interpreted as the motionally averaged spectrum of the anisotropic ${mathrm{V}}^{4+}$ spectrum. The data are analyzed in terms of Ham's theory of the dynamic Jahn-Teller effect for a $^{2}$E state. A sharp optical line at 6681 ${mathrm{cm}}^{mathrm{ensuremath{-}}1}$ has been found in MCD absorption. On this line the MCD-ESR of ${mathrm{V}}^{4+}$ is observed, which identifies the line as being related to ${mathrm{V}}^{4+}$. It is interpreted as the zero-phonon line of the ${mathrm{V}}^{4+}$ $^{2}$E${ensuremath{rightarrow}}^{2}$${mathit{T}}_{2}$ crystal-field transition." @default.
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- W2018148366 date "1994-12-15" @default.
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- W2018148366 title "Identification of the neutral<mml:math xmlns:mml=http://www.w3.org/1998/Math/MathML display=inline><mml:mrow><mml:msup><mml:mrow><mml:mi mathvariant=normal>V</mml:mi></mml:mrow><mml:mrow><mml:mn>4</mml:mn><mml:mo>+</mml:mo></mml:mrow></mml:msup></mml:mrow></mml:math>impurity in cubic 3<i>C</i>-SiC by electron-spin resonance and optically detected magnetic resonance" @default.
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- W2018148366 doi "https://doi.org/10.1103/physrevb.50.18034" @default.
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