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- W2018178369 abstract "Intensively coloured stibinidene complexes (LnM)2SbR (LnM = (CO)5Cr; R = tBu, Cl, I, EtS. LnM = C5H5(CO)2Mn; R = Cl. LnM = CH3C5H4(CO)2Mn; R = Br) which contain trigonally planar coordinated Sb(+1) with the stibanediyl ligand stabilized by M ⋯ Sb(R) ⋯ M-π-bonding have been obtained. Their synthesis and properties as well as an X-ray structure determination of [CH3C5H4(CO)2Mn]2SbBr are described. Intensiv gefärbte Stibiniden-Komplexe (LnM)2SbR (LnM = (CO)5Cr; R =tBu, Cl, I, EtS. LnM = C5H5(CO)2Mn; R = Cl. LnM = CH3C5H4(CO)2Mn; R= Br) mit trigonal planar koordiniertem Sb(+1) wurden dargestellt. In ihnen ist der Stibandiyl-Ligand durch ein M⋯Sb(R)⋯M-π-Bindungssystem stabilisiert. Synthese und Eigenschaften der neuen Verbindungen sowie die Röntgenstrukturanalyse von [CH3C5H4(CO)2Mn]2SbBr werden beschrieben." @default.
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- W2018178369 date "1984-01-01" @default.
- W2018178369 modified "2023-10-17" @default.
- W2018178369 title "Stibinidenkomplexe: Verbindungen mit trigonal planar koordiniertem antimon" @default.
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- W2018178369 doi "https://doi.org/10.1016/s0022-328x(00)99477-4" @default.
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